(环庚三烯)(环戊二烯基)锰
外观
(环庚三烯)(环戊二烯基)锰 | |
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识别 | |
CAS号 | 52308-70-0 ![]() |
性质 | |
外观 | 红黑色针状晶体[1] |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
(环庚三烯)(环戊二烯基)锰是一种有机锰化合物,化学式为C12H13Mn。它可由环庚三烯和三羰基环戊二烯锰在正庚烷中反应制得。[1]它和白磷在1,3-二异丙基苯中反应,可以得到[(C5H5)4Mn4P4]。[2]
参考文献
[编辑]- ^ 1.0 1.1 Peter L. Pauson and John A. Segal. (η-Cycloheptatriene)- and (η-cycloheptatrienylium)-(η-cyclopentadienyl)manganese. Formation of cyclic triene complexes by photochemical displacement of three carbonyl groups from tricarbonyl-(η-cyclopentadienyl)manganese. J. Chem. Soc., Dalton Trans., 1975, 2387-2392. doi:10.1039/DT9750002387
- ^ Sebastian Heinl; et al. The synthesis of the heterocubane cluster [{CpMn}4(μ3-P)4] as a tetrahedral shaped starting material for the formation of polymeric coordination compounds. Chem. Commun., 2015,51, 13474-13477. doi:10.1039/C5CC04800A.
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