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4-硝基苯并-15-冠-5

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4-硝基苯并-15-冠-5
识别
CAS号 60835-69-0  checkY
SMILES
 
  • O=N(=O)C1=CC=C2OCCOCCOCCOCCOC2=C1
性质
化学式 C14H19NO7
摩尔质量 313.3 g·mol−1
熔点 95-96 °C[1]
相关物质
相关化学品 15-冠-5
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

4-硝基苯并-15-冠-5是一种有机化合物,化学式为C14H19NO7。它可由苯并-15-冠-5维基数据Q27117143硝化制得。[2][3]在钯催化下,它可以被水合肼还原为4-氨基苯并-15-冠-5。[4]

参考文献

[编辑]
  1. ^ Sadovskaya, N. Yu.; Glushko, V. N.; Retivov, V. M.; Belus’, S. K.; Grokhovskii, V. V. Synthesis and properties of macroheterocyclic azomethines based on 4-aminobenzo-15-crown-5. Russian Journal of General Chemistry. 2015-12, 85 (12): 2771–2777. ISSN 1070-3632. doi:10.1134/S1070363215120191 (英语). 
  2. ^ Glushko, Valentina N.; Sadovskaya, Natalya Yu.; Kozhuhov, Vadim I.; Blokhina, Lidiya I.; Antropova, Irina A.; Petina, Ekaterina S.; Retiviov, Vasiliy М.; Melnikova, Ekaterina Yu. Production of Macrocyclic Polyether Benzo-15-Crown-5 and its Functional Derivatives. Oriental Journal of Chemistry. 2017-08-28, 33 (04): 1689-1697. doi:10.13005/ojc/330413. 
  3. ^ Yang, Jye-Shane; Hwang, Chung-Yu; Chen, Mon-Yao. Bimodal fluorescence signaling based on control of the excited-state conformational twisting and the ground-state protonation processes. Tetrahedron Letters. 2007-04-23, 48 (17): 3097-3102. ISSN 0040-4039. doi:10.1016/j.tetlet.2007.02.120. 
  4. ^ Bunchuay, Thanthapatra; Docker, Andrew; Eiamprasert, Utt; Surawatanawong, Panida; Brown, Asha; Beer, Paul D. Chalcogen Bond Mediated Enhancement of Cooperative Ion‐Pair Recognition. Angewandte Chemie International Edition. 2020-07-13, 59 (29): 12007-12012. ISSN 1433-7851. doi:10.1002/anie.202001125 (英语).