N-三氟乙酰基色胺
| N-三氟乙酰基色胺 | |
|---|---|
| 识别 | |
| CAS号 | 319-76-6 
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| SMILES |
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| 性质 | |
| 化学式 | C12H11F3N2O |
| 摩尔质量 | 256.22 g·mol−1 |
| 外观 | 无色油状物[1] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
N-三氟乙酰基色胺是一种有机化合物，化学式为C12H11F3N2O。它可由色胺和三氟乙酸酐在吡啶存在下反应制得。[1]它可以被2,3-二氯-5,6-二氰对苯醌氧化为N-三氟乙酰基-8-氧代色胺，[2]或被高碘酸钠氧化为N-[2-(3-三氟乙酰氨基-1-氧代丙基)苯基]甲酰胺。[3]
参考文献
[编辑]- ^ 1.0 1.1 James D. White; et al. Tandem Intramolecular Photocycloaddition−Retro-Mannich Fragmentation as a Route to Spiro[pyrrolidine-3,3′-oxindoles]. Total Synthesis of (±)-Coerulescine, (±)-Horsfiline, (±)-Elacomine, and (±)-6-Deoxyelacomine. J. Org. Chem. 2010, 75, 11, 3569–3577. doi:10.1021/jo1002714.
- ^ Szabo, Timea; et al. First reported propylphosphonic anhydride (T3P) mediated Robinson-Gabriel cyclization. Synthesis of natural and unnatural 5-(3-indolyl)oxazoles. Tetrahedron Letters (2019), 60(20), 1353-1356. doi:10.1016/j.tetlet.2019.04.024.
- ^ He, Tao; et al. Aggregation-induced emission enhancement of polycyclic aromatic alkaloid derivatives and the crucial role of excited-state proton-transfer. Chemical Communications (2011), 47(10), 2907-2909. doi:10.1039/C0CC04827E.